COMPOSITOS METAL/POLIMERO: PODEROSOS ALIADOS EN LA ESPECTROSCOPIA RAMAN MEJORADA EN SUPERFICIE
DOI:
https://doi.org/10.32399/icuap.rdic.2448-5829.2023.27.1173Palabras clave:
Polímeros, Nanoparticulas metálicas, sustratos SERS, DetecciónResumen
Los polímeros y las nanopartículas metálicas se pueden combinar para formar diferentes materiales con características específicas. En este trabajo se revisan a grandes rasgos los conceptos fundamentales para la formación de compositos metal/polímero, con énfasis en sistemas con aplicación potencial en la Espectroscopia Raman Mejorada en Superficie (SERS, por sus siglas en inglés; Surface-Enhanced Raman Spectroscopy). Se presentan brevemente las teorías básicas de los mecanismos de mejora de SERS. Se resumen de manera general los avances más interesantes en sustratos SERS metal/polímero. Además, se analizan las principales aplicaciones SERS en múltiples campos de la investigación, incluidas la detección biomolecular, el diagnóstico médico, las ciencias forenses, la detección de contaminantes orgánicos, la seguridad alimenticia, entre otros. Se finaliza con una discusión de oportunidades prometedoras para la investigación de sustratos SERS basados en compositos metal/polimero en el futuro.
Citas
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Braun, G. B., Lee, S. J., Laurence, T., Fera, N., Fabris, L., Bazan, G. C., Moskovits, M., & Reich, N. O. (2009). Generalized Approach to SERS-Active Nanomaterials via Controlled Nanoparticle Linking, Polymer Encapsulation, and Small-Molecule Infusion. The Journal of Physical Chemistry C, 113(31), 13622–13629. https://doi.org/10.1021/jp903399p
Chen, L., Yan, H., Xue, X., Jiang, D., Cai, Y., Liang, D., Jung, Y. M., Han, X. X., & Zhao, B. (2017). Surface-Enhanced Raman Scattering (SERS) Active Gold Nanoparticles Decorated on a Porous Polymer Filter. Applied Spectroscopy, 71(7), 1543–1550. https://doi.org/10.1177/0003702817703293
Chen, T., Wang, H., Chen, G., Wang, Y., Feng, Y., Teo, W. S., Wu, T., & Chen, H. (2010). Hotspot-Induced Transformation of Surface-Enhanced Raman Scattering Fingerprints. ACS Nano, 4(6), 3087–3094. https://doi.org/10.1021/nn100269v
Fateixa, S., Girão, A. V., Nogueira, H. I. S., & Trindade, T. (2011). Polymer based silver nanocomposites as versatile solid film and aqueous emulsion SERS substrates. Journal of Materials Chemistry, 21(39), 15629–15636. https://doi.org/10.1039/c1jm12444g
Fateixa, S., Pinheiro, P. C., Nogueira, H. I. S., & Trindade, T. (2013). Composite blends of gold nanorods and poly( t-butylacrylate) beads as new substrates for SERS. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 113, 100–106. https://doi.org/10.1016/j.saa.2013.04.070
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Kim, J., Twaddle, K. M., Cermak, L. M., Jang, W., Yun, J., & Byun, H. (2016). Photothermal heating property of gold nanoparticle loaded substrates and their SERS response. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 498, 20–29. https://doi.org/10.1016/j.colsurfa.2016.03.025
Lee, A., Dubinsky, S., Tumarkin, E., Moulin, M., Beharry, A. A., & Kumacheva, E. (2011). Multifunctional Hybrid Polymer-Based Porous Materials. Advanced Functional Materials, 21(11), 1959–1969. https://doi.org/10.1002/adfm.201002453
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Pinheiro, P. C., Fateixa, S., Nogueira, H. I. S., & Trindade, T. (2015). SERS studies of DNA nucleobases using new silver poly(methyl methacrylate) nanocomposites as analytical platforms. Journal of Raman Spectroscopy, 46(1), 47–53. https://doi.org/10.1002/jrs.4589
Pryshchepa, O., Pomastowski, P., & Buszewski, B. (2020). Silver nanoparticles: Synthesis, investigation techniques, and properties. Advances in Colloid and Interface Science, 284, 87–100. https://doi.org/10.1016/j.cis.2020.102246
Qian, X., Li, J., & Nie, S. (2009). Stimuli-Responsive SERS Nanoparticles: Conformational Control of Plasmonic Coupling and Surface Raman Enhancement. Journal of the American Chemical Society, 131(22), 7540–7541. https://doi.org/10.1021/ja902226z
Quaroni, L., & Chumanov, G. (1999). Preparation of Polymer-Coated Functionalized Silver Nanoparticles. Journal of the American Chemical Society, 121(45), 10642–10643. https://doi.org/10.1021/ja992088q
Sansone, L., Campopiano, S., Pannico, M., Giordano, M., Musto, P., & Iadicicco, A. (2021). Photonic bandgap influence on the SERS effect in metal-dielectric colloidal crystals optical fiber probe. Sensors and Actuators, B: Chemical, 345(January). https://doi.org/10.1016/j.snb.2021.130149
Strozyk, M. S., Jimenez de Aberasturi, D., & Liz-Marzán, L. M. (2018). Composite Polymer Colloids for SERS-Based Applications. The Chemical Record, 18(7–8), 807–818. https://doi.org/10.1002/tcr.201700082
Xie, L., Zeng, H., Zhu, J., Zhang, Z., Sun, H., Xia, W., & Du, Y. (2022). State of the art in flexible SERS sensors toward label-free and onsite detection: from design to applications. Nano Research, 15(5), 4374–4394. https://doi.org/10.1007/s12274-021-4017-4
Yin, J., Wu, T., Song, J., Zhang, Q., Liu, S., Xu, R., & Duan, H. (2011). SERS-Active Nanoparticles for Sensitive and Selective Detection of Cadmium Ion (Cd 2+ ). Chemistry of Materials, 23(21), 4756–4764. https://doi.org/10.1021/cm201791r
Yu, W. W., & White, I. M. (2012). A simple filter-based approach to surface enhanced Raman spectroscopy for trace chemical detection. The Analyst, 137(5), 1168. https://doi.org/10.1039/c2an15947c
Zhu, W., Wu, Y., Yan, C., Wang, C., Zhang, M., & Wu, Z. (2013). Facile synthesis of mono-dispersed polystyrene (PS)/Ag composite microspheres via modified chemical reduction. Materials, 6(12), 5625–5638. https://doi.org/10.3390/ma6125625
Braun, G. B., Lee, S. J., Laurence, T., Fera, N., Fabris, L., Bazan, G. C., Moskovits, M., & Reich, N. O. (2009). Generalized Approach to SERS-Active Nanomaterials via Controlled Nanoparticle Linking, Polymer Encapsulation, and Small-Molecule Infusion. The Journal of Physical Chemistry C, 113(31), 13622–13629. https://doi.org/10.1021/jp903399p
Chen, L., Yan, H., Xue, X., Jiang, D., Cai, Y., Liang, D., Jung, Y. M., Han, X. X., & Zhao, B. (2017). Surface-Enhanced Raman Scattering (SERS) Active Gold Nanoparticles Decorated on a Porous Polymer Filter. Applied Spectroscopy, 71(7), 1543–1550. https://doi.org/10.1177/0003702817703293
Chen, T., Wang, H., Chen, G., Wang, Y., Feng, Y., Teo, W. S., Wu, T., & Chen, H. (2010). Hotspot-Induced Transformation of Surface-Enhanced Raman Scattering Fingerprints. ACS Nano, 4(6), 3087–3094. https://doi.org/10.1021/nn100269v
Fateixa, S., Girão, A. V., Nogueira, H. I. S., & Trindade, T. (2011). Polymer based silver nanocomposites as versatile solid film and aqueous emulsion SERS substrates. Journal of Materials Chemistry, 21(39), 15629–15636. https://doi.org/10.1039/c1jm12444g
Fateixa, S., Pinheiro, P. C., Nogueira, H. I. S., & Trindade, T. (2013). Composite blends of gold nanorods and poly( t-butylacrylate) beads as new substrates for SERS. Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 113, 100–106. https://doi.org/10.1016/j.saa.2013.04.070
Kim, D. J., Jeon, T. Y., Park, S.-G., Han, H. J., Im, S. H., Kim, D.-H., & Kim, S.-H. (2017). Uniform Microgels Containing Agglomerates of Silver Nanocubes for Molecular Size-Selectivity and High SERS Activity. Small, 13(23), 1604048. https://doi.org/10.1002/smll.201604048
Kim, J., Twaddle, K. M., Cermak, L. M., Jang, W., Yun, J., & Byun, H. (2016). Photothermal heating property of gold nanoparticle loaded substrates and their SERS response. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 498, 20–29. https://doi.org/10.1016/j.colsurfa.2016.03.025
Lee, A., Dubinsky, S., Tumarkin, E., Moulin, M., Beharry, A. A., & Kumacheva, E. (2011). Multifunctional Hybrid Polymer-Based Porous Materials. Advanced Functional Materials, 21(11), 1959–1969. https://doi.org/10.1002/adfm.201002453
Manojkumar, K., Sivaramakrishna, A., & Vijayakrishna, K. (2016). A short review on stable metal nanoparticles using ionic liquids, supported ionic liquids, and poly(ionic liquids). Journal of Nanoparticle Research, 18(4). https://doi.org/10.1007/s11051-016-3409-y
Petryayeva, E., & Krull, U. J. (2011). Localized surface plasmon resonance: Nanostructures, bioassays and biosensing-A review. Analytica Chimica Acta, 706(1), 8–24. https://doi.org/10.1016/j.aca.2011.08.020
Pinheiro, P. C., Fateixa, S., Nogueira, H. I. S., & Trindade, T. (2015). SERS studies of DNA nucleobases using new silver poly(methyl methacrylate) nanocomposites as analytical platforms. Journal of Raman Spectroscopy, 46(1), 47–53. https://doi.org/10.1002/jrs.4589
Pryshchepa, O., Pomastowski, P., & Buszewski, B. (2020). Silver nanoparticles: Synthesis, investigation techniques, and properties. Advances in Colloid and Interface Science, 284, 87–100. https://doi.org/10.1016/j.cis.2020.102246
Qian, X., Li, J., & Nie, S. (2009). Stimuli-Responsive SERS Nanoparticles: Conformational Control of Plasmonic Coupling and Surface Raman Enhancement. Journal of the American Chemical Society, 131(22), 7540–7541. https://doi.org/10.1021/ja902226z
Quaroni, L., & Chumanov, G. (1999). Preparation of Polymer-Coated Functionalized Silver Nanoparticles. Journal of the American Chemical Society, 121(45), 10642–10643. https://doi.org/10.1021/ja992088q
Sansone, L., Campopiano, S., Pannico, M., Giordano, M., Musto, P., & Iadicicco, A. (2021). Photonic bandgap influence on the SERS effect in metal-dielectric colloidal crystals optical fiber probe. Sensors and Actuators, B: Chemical, 345(January). https://doi.org/10.1016/j.snb.2021.130149
Strozyk, M. S., Jimenez de Aberasturi, D., & Liz-Marzán, L. M. (2018). Composite Polymer Colloids for SERS-Based Applications. The Chemical Record, 18(7–8), 807–818. https://doi.org/10.1002/tcr.201700082
Xie, L., Zeng, H., Zhu, J., Zhang, Z., Sun, H., Xia, W., & Du, Y. (2022). State of the art in flexible SERS sensors toward label-free and onsite detection: from design to applications. Nano Research, 15(5), 4374–4394. https://doi.org/10.1007/s12274-021-4017-4
Yin, J., Wu, T., Song, J., Zhang, Q., Liu, S., Xu, R., & Duan, H. (2011). SERS-Active Nanoparticles for Sensitive and Selective Detection of Cadmium Ion (Cd 2+ ). Chemistry of Materials, 23(21), 4756–4764. https://doi.org/10.1021/cm201791r
Yu, W. W., & White, I. M. (2012). A simple filter-based approach to surface enhanced Raman spectroscopy for trace chemical detection. The Analyst, 137(5), 1168. https://doi.org/10.1039/c2an15947c
Zhu, W., Wu, Y., Yan, C., Wang, C., Zhang, M., & Wu, Z. (2013). Facile synthesis of mono-dispersed polystyrene (PS)/Ag composite microspheres via modified chemical reduction. Materials, 6(12), 5625–5638. https://doi.org/10.3390/ma6125625
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2023-09-01
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Matamoros-Ambrocio, M. ., Sánchez-Mora, E. ., & Gomez-Barojas, E. . (2023). COMPOSITOS METAL/POLIMERO: PODEROSOS ALIADOS EN LA ESPECTROSCOPIA RAMAN MEJORADA EN SUPERFICIE. RD-ICUAP, 9(27), 22–32. https://doi.org/10.32399/icuap.rdic.2448-5829.2023.27.1173
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